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Stainless Steel and Nickel Alloy Fastener Selection Guide
Core Material Selection Principle: Performance and Environmental Matching
When selecting fastener materials, strength should not be the only consideration; the service environment must be comprehensively evaluated.
Core considerations include:
Define the Usage Environment: Determine the temperature range (e.g., -40°C to 300°C) and the type of corrosive media (e.g., dry air, fresh water, seawater, chlorides).
Determine Performance Priority: Rank requirements as "Corrosion Resistance > Temperature Tolerance > Strength > Non-magnetic/Galling Resistance" to clarify core needs.
Match Material Category: Based on environmental and performance requirements, filter corresponding groups from categories like Austenitic, Duplex, Martensitic, etc.
Cost Effectiveness: Select the most economical material that meets the usage requirements.
I. Material Selection by Stainless Steel Microstructure Type
1. Austenitic Stainless Steel (Class A: A1-A5, A8)
Core Characteristics: Non-magnetic (cold working may produce weak residual magnetism, removable by heat treatment), cannot be hardened by quenching, relies on work hardening for improved performance. Generally good corrosion resistance, some groups (e.g., A8) can withstand marine and high chloride environments.
| Group | Typical Application Scenarios | Key Limitations |
|---|---|---|
| A1 | Only for non-corrosive environments requiring frequent machining (e.g., ordinary indoor dry equipment) | High sulfur content, poor corrosion resistance, avoid chlorides, non-oxidizing acids |
| A2 | General purpose (e.g., architectural decoration, appliances, ordinary outdoor environments without salt spray) | Not resistant to pool chlorides, marine environments, carbon content >0.03% |
| A3 | General purpose scenarios requiring heat resistance (≤350°C) (e.g., oven parts, water heater components) | Not resistant to chlorides, non-oxidizing acid environments |
| A4 | Mildly corrosive environments (e.g., lightly industrially polluted areas, freshwater pipelines) | Contains Mo, can tolerate slight chlorides, but still avoid swimming pools |
| A5 | Scenarios requiring heat resistance (≤350°C) and mild corrosion resistance (e.g., chemical pipelines with mild acid, medium-temperature food processing equipment parts) | Corrosion resistance similar to A4, can tolerate slight chlorides, still avoid... Ti/Nb forms stabilized structure, heat resistance better than A4 |
| A8 | Highly corrosive environments (e.g., marine engineering, swimming pool equipment, chemical pipelines containing chlorine) | "6% Mo" stainless steel, resistant to pitting, stress corrosion cracking |
2. Martensitic Stainless Steel (Class C: C1, C2, C3)
Core Characteristics: Can be strengthened by quenching and tempering, high strength but corrosion resistance weaker than Austenitic stainless steel, strongly magnetic. Poor low-temperature toughness, use cautiously below 0°C.
| Group | Typical Application Scenarios | Key Limitations |
|---|---|---|
| C1 | Low corrosion, high load scenarios (e.g., ordinary mechanical transmission parts, indoor structural steel bolts) | Limited corrosion resistance, avoid moisture |
| C2 | Medium load scenarios with slightly better corrosion resistance than C1 (e.g., fasteners for lightly humid indoor equipment) | Still need to avoid corrosive environments, |
| C3 | Low corrosion scenarios requiring frequent machining (e.g., internal connecting parts for ordinary machinery) | High sulfur content, corrosion resistance is... |
3. Ferritic Stainless Steel (Class F: F1)
Core Characteristics: Slightly strengthened by cold working, magnetic, lower cost than Austenitic stainless steel. Corrosion resistance weaker than A2, A3, poor low-temperature toughness (not suitable below -20°C).
F1 Applicable Scenarios: Low cost, low corrosion, non-cryogenic scenarios (e.g., indoor simple brackets, non-load-bearing decorative fasteners).
4. Duplex (Austenitic + Ferritic) Stainless Steel (Class D: D2, D4, D6, D8)
Core Characteristics: Higher strength than Austenitic stainless steel, significantly better stress corrosion cracking resistance than A1-A5. Higher number indicates better corrosion resistance; D8 (Super Duplex) corrosion resistance is comparable to A8.
| Group | Typical Application Scenarios | Key Limitations |
|---|---|---|
| D2, D4 (Lean Duplex) | Mild corrosion, medium load scenarios (e.g., freshwater pipelines, ordinary chemical equipment) | Corrosion resistance equivalent to A2, A4 respectively, cost lower than A8 |
| D6 (Standard Duplex) | Moderate corrosion scenarios (e.g., primary seawater desalination equipment, structural parts in moderately industrially polluted areas) | Better pitting and crevice corrosion resistance than A4 |
| D8 (High Duplex/Super Duplex) | Highly corrosive, high load scenarios (e.g., deep-sea equipment, high salt spray marine engineering) | Corrosion resistance close to A8, higher strength |
5. High-Temperature Stainless Steels and Nickel Alloys (CH0~CH2, V/VH/VW, SD, SB, 718)
Core Characteristics: Temperature range (High temp: 300°C~550°C; Very high temp: >550°C), must have sufficient oxidation resistance, high-temperature corrosion resistance, and creep resistance.
| Group | Temperature Tolerance / Typical Application Scenarios |
|---|---|
| CH0, CH1, CH2 | ≤500°C; Medium temperature equipment (e.g., boiler attachments, hot oil pipeline fasteners) |
| V, VH, VW | Medium-high temperature mechanical components (e.g., turbine linkages) |
| (Note: D8 listed here seems misplaced; likely refers to another high-temp alloy like a specific Ni-alloy) | >550°C; Aerospace, high-end chemical furnaces, and other extreme high-temperature scenarios |
II. Material Selection for Special Performance Needs
Stress Corrosion Cracking (SCC) Risk Scenarios: Chloride-containing environments (e.g., swimming pools, marine), high temperature and humid environments. Recommended materials: D6/D8 Duplex steel, A8 Austenitic steel; Avoid: A1-A5 Austenitic steels.
Pitting/Crevice Corrosion Resistance: Pitting Resistance Equivalent Number (PREN) = %Cr + 3.3 * %Mo + 16 * %N; For Duplex steels containing Tungsten (W): PREN = %Cr + 3.3 * (%Mo + 0.5 * %W) + 16 * %N. Recommended materials: Groups with high PREN values (e.g., A8, D8, D6), suitable for chemical media containing chlorine, seawater environments.
Intergranular Corrosion Resistance: High-risk conditions: Carbon content > 0.03% + temperature range 550°C - 925°C (e.g., after welding, high temperature use). Recommended materials: Low-carbon groups: A2L, A4L (C ≤ 0.03%); Stabilized groups: A3, A5 (contain Ti/Nb, combines with carbon to prevent intergranular corrosion); Duplex steels: All groups D2-D8.
Low/Non-Magnetic Requirements: Core materials: Austenitically stable grades, such as A2L (4311-304-53-I), A4L (4406-316-53-I), QN1803 (Nitrogen-alloyed Austenitic steel). Note: Cold working can produce weak residual magnetism; subsequent heat treatment can remove it if non-magnetic is required, or confirm permeability with supplier in advance (require relative permeability close to 1.0).
High Strength + Anti-Galling: Recommended materials: Sorbitic high-strength stainless structural steel (S1 group): Suitable for large diameter, high load fasteners (e.g., large structural steel bolts), stable torque coefficient; QN1803 (A2 group nitrogen steel): High strength and weakly magnetic, low risk of galling during installation, suitable for frequent assembly/disassembly scenarios.
III. Common Stainless Steel Grades for Fasteners
Table 1: Cold Heading Fastener Stainless Steel Grades - Austenitic
| Class | Group | ISC Code | Euronorm Material Number | Euronorm Designation | ASTM UNS | US Common Grade | GB Code (China) | ||
|---|---|---|---|---|---|---|---|---|---|
| Sulfurized Austenitic | A1 | 4305-303-00-1 | 1.4305 | X8CrNiS18-9 | S30300 | 303 | Y1Cr18Ni9 (approx.) | ||
| 4570-303-31-1 | 1.4570 | X6CrNiCuS18-9-2 | S30331 | 303Cu | - | ||||
| General Purpose Austenitic | A2L | 4307-304-03-1 | 1.4307 | X2CrNi18-9 | S30403 | 304L | 022Cr19Ni10 | ||
| 4306-304-03-1 | 1.4306 | X2CrNi19-11 | S30403 | 304L | 022Cr19Ni10 | ||||
| 4311-304-53-I | 1.4311 | X2CrNiN18-9 | S30453 | 304LN | 022Cr19Ni10N | ||||
| A2 | 4301-304-00-I | 1.4301 | X5CrNi18-10 | S30400 | 304 | 06Cr19Ni10 | |||
| 4567-804-301 | 1.4567 | X3CrNiCu18-9-4 | S30430 | 304Cu | 06Cr18Ni9Cu3 | ||||
| 4560-304-75-E | 1.4560 | X3CrNiCu19-9-2 | - | 304Cu | - | ||||
| 4303-305-00-1 | 1.4303 | X4CrNi18-12 | S30500 | 305 | 18Cr15Ni12 | ||||
| Stabilized Austenitic | A3 | 4550-347-00-1 | 1.4550 | X6CrNiNb18-10 | S34700 | 347 | 06Cr18Ni11Nb | ||
| 4541-321-00-1 | 1.4541 | X6CrNiTi18-10 | S32100 | 321 | 06Cr18Ni11Ti | ||||
| Molybdenum Austenitic | A4L | 4401-315-00-1 | 1.4401 | X5CrNiMo17-12-2 | S31600 | 316 | 06Cr17Ni12Mo2 | ||
| 4404-315-03-1 | 1.4404 | X2CrNiMo17-12-2 | S31603 | 316L | 022Cr17Ni12Mo2 | ||||
| 4406-316-53-1 | 1.4406 | X2CrNiMoN17-11-2 | S31653 | 316LN | 022Cr17Ni12Mo2N | ||||
| 4432-316-03-1 | 1.4432 | X2CrNiMo17-12-3 | S31603 | 316L | 022Cr17Ni14Mo2 | ||||
| A4L/A4 | 4435-316-91-1 | 1.4435 | X2CrNiMo18-14-3 | S31603 | 316L | 022Cr17Ni14Mo3 | |||
| 4436-316-00-1 | 1.4436 | X3CrNiMo17-13-3 | S31600 | 316 | 06Cr17Ni12Mo3 | ||||
| A4 | 4578-316-76-E | 1.4578 | X3CrNiCuMo17-11-3-2 | - | - | - | |||
| Stabilized Mo Austenitic | A5 | 4571-316-35-1 | 1.4571 | X6CrNiMoTi17-12-2 | S31635 | 316Ti | 06Cr17Ni12Mo2Ti | ||
| High-Mo Super Austenitic | A8 | 4478-083-67-U | 1.4478 | X2NiCrMoN25-21-7 | N08367 | AL-6XN® / N08367 | - | ||
| 4529-089-26-1 | 1.4529 | X1NiCrMoCuN25-20-7 | N08926 | 926 / Alloy 926 | - | ||||
| 4547-312-54-1 | 1.4547 | X1CrNiMoCuN20-18-7 | S31254 | 254 SMO / F44 | 015Cr20Ni18Mo6CuN |
Table 2: Cold Heading Fastener Stainless Steel Grades - Ferritic / Martensitic / Duplex
| Category | Group | ISC Code | Euronorm Material Number | Euronorm Designation | ASTM UNS | US Common Grade | GB Code (China) |
|---|---|---|---|---|---|---|---|
| General Purpose Martensitic | C1 | 4006-410-CO-I | 1.4006 | X12Cr13 | S41000 | 410 | 12Cr13 |
| C1 | 4000-410-08-1 | 1.4000 | X6Cr13 | S41008 | 410S | 06Cr13 | |
| C1, CH0 | 4021-420-00-1 | 1.4021 | X20Cr13 | S42000 | 420 | 20Cr13 | |
| C1, CH1 | 4028-420-00-1 | 1.4028 | X30Cr13 | S42000 | 420 | 30Cr13 | |
| C1 | 4034-420-CO-I | 1.4034 | X46Cr13 | S42000 | 420 | 40Cr13 | |
| High-Temp Martensitic? | V, or VH | 4923-422-77-E | 1.4923 | X22CrMoV12-1 | - | - | - |
| High-Cr Martensitic | C3, CH2 | 4057-431-0D-X | 1.4057 | X17CrNi16-2 | S43100 | 431 | 17Cr16Ni2 |
| Free-Machining Martensitic | C4 | 4005-416-00-1 | 1.4005 | X12CrS13 | S41600 | 416 | Y1Cr13 |
| C4 | 4029-420-20-1 | 1.4029 | X29CrS13 | S42020 | 420F | Y3Cr13 | |
| Ferritic | F1 | 4016-430-00-1 | 1.4016 | X6Cr17 | S43000 | 430 | 10Cr17 |
| F1 | 4511-430-71-I | 1.4511 | X3CrNb17 | - | - | 028Cr17? (Stabilized) | |
| F1 | 4113-434-00-1 | 1.4113 | X6CrMo17-1 | S43400 | 434 | 10Cr17Mo | |
| F1 | 4526-436-CO-I | 1.4526 | X6CrMoNb17-1 | S43600 | 436 | 028Cr17MoNb? | |
| F1 | 4509-439-4D-X | 1.4509 | X2CrTiNb18 | S43940 | 439 / 441? | 022Cr18Ti? | |
| F1 | 4521-444-00-I | 1.4521 | X2CrMoTi18-2 | S44400 | 444 | 019Cr18MoTi? | |
| Duplex | D2 | 4482-320-01-X | 1.4482 | X2CrMnNiMoN21-5-3 | S32001 | 2001 / LDX 2101® | - |
















