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Stainless Steel and Nickel Alloy Fastener Selection Guide

Core Material Selection Principle: Performance and Environmental Matching

When selecting fastener materials, strength should not be the only consideration; the service environment must be comprehensively evaluated.

Core considerations include:

  • Define the Usage Environment: Determine the temperature range (e.g., -40°C to 300°C) and the type of corrosive media (e.g., dry air, fresh water, seawater, chlorides).

  • Determine Performance Priority: Rank requirements as "Corrosion Resistance > Temperature Tolerance > Strength > Non-magnetic/Galling Resistance" to clarify core needs.

  • Match Material Category: Based on environmental and performance requirements, filter corresponding groups from categories like Austenitic, Duplex, Martensitic, etc.

  • Cost Effectiveness: Select the most economical material that meets the usage requirements.

I. Material Selection by Stainless Steel Microstructure Type

1. Austenitic Stainless Steel (Class A: A1-A5, A8)

Core Characteristics: Non-magnetic (cold working may produce weak residual magnetism, removable by heat treatment), cannot be hardened by quenching, relies on work hardening for improved performance. Generally good corrosion resistance, some groups (e.g., A8) can withstand marine and high chloride environments.

GroupTypical Application ScenariosKey Limitations
A1Only for non-corrosive environments requiring frequent machining (e.g., ordinary indoor dry equipment)High sulfur content, poor corrosion resistance, avoid chlorides, non-oxidizing acids
A2General purpose (e.g., architectural decoration, appliances, ordinary outdoor environments without salt spray)Not resistant to pool chlorides, marine environments, carbon content >0.03%
A3General purpose scenarios requiring heat resistance (≤350°C) (e.g., oven parts, water heater components)Not resistant to chlorides, non-oxidizing acid environments
A4Mildly corrosive environments (e.g., lightly industrially polluted areas, freshwater pipelines)Contains Mo, can tolerate slight chlorides, but still avoid swimming pools
A5Scenarios requiring heat resistance (≤350°C) and mild corrosion resistance (e.g., chemical pipelines with mild acid, medium-temperature food processing equipment parts)Corrosion resistance similar to A4, can tolerate slight chlorides, still avoid... Ti/Nb forms stabilized structure, heat resistance better than A4
A8Highly corrosive environments (e.g., marine engineering, swimming pool equipment, chemical pipelines containing chlorine)"6% Mo" stainless steel, resistant to pitting, stress corrosion cracking

2. Martensitic Stainless Steel (Class C: C1, C2, C3)

Core Characteristics: Can be strengthened by quenching and tempering, high strength but corrosion resistance weaker than Austenitic stainless steel, strongly magnetic. Poor low-temperature toughness, use cautiously below 0°C.

GroupTypical Application ScenariosKey Limitations
C1Low corrosion, high load scenarios (e.g., ordinary mechanical transmission parts, indoor structural steel bolts)Limited corrosion resistance, avoid moisture
C2Medium load scenarios with slightly better corrosion resistance than C1 (e.g., fasteners for lightly humid indoor equipment)Still need to avoid corrosive environments,
C3Low corrosion scenarios requiring frequent machining (e.g., internal connecting parts for ordinary machinery)High sulfur content, corrosion resistance is...

3. Ferritic Stainless Steel (Class F: F1)

Core Characteristics: Slightly strengthened by cold working, magnetic, lower cost than Austenitic stainless steel. Corrosion resistance weaker than A2, A3, poor low-temperature toughness (not suitable below -20°C).

F1 Applicable Scenarios: Low cost, low corrosion, non-cryogenic scenarios (e.g., indoor simple brackets, non-load-bearing decorative fasteners).

4. Duplex (Austenitic + Ferritic) Stainless Steel (Class D: D2, D4, D6, D8)

Core Characteristics: Higher strength than Austenitic stainless steel, significantly better stress corrosion cracking resistance than A1-A5. Higher number indicates better corrosion resistance; D8 (Super Duplex) corrosion resistance is comparable to A8.

GroupTypical Application ScenariosKey Limitations
D2, D4 (Lean Duplex)Mild corrosion, medium load scenarios (e.g., freshwater pipelines, ordinary chemical equipment)Corrosion resistance equivalent to A2, A4 respectively, cost lower than A8
D6 (Standard Duplex)Moderate corrosion scenarios (e.g., primary seawater desalination equipment, structural parts in moderately industrially polluted areas)Better pitting and crevice corrosion resistance than A4
D8 (High Duplex/Super Duplex)Highly corrosive, high load scenarios (e.g., deep-sea equipment, high salt spray marine engineering)Corrosion resistance close to A8, higher strength

5. High-Temperature Stainless Steels and Nickel Alloys (CH0~CH2, V/VH/VW, SD, SB, 718)

Core Characteristics: Temperature range (High temp: 300°C~550°C; Very high temp: >550°C), must have sufficient oxidation resistance, high-temperature corrosion resistance, and creep resistance.

GroupTemperature Tolerance / Typical Application Scenarios
CH0, CH1, CH2≤500°C; Medium temperature equipment (e.g., boiler attachments, hot oil pipeline fasteners)
V, VH, VWMedium-high temperature mechanical components (e.g., turbine linkages)
(Note: D8 listed here seems misplaced; likely refers to another high-temp alloy like a specific Ni-alloy)>550°C; Aerospace, high-end chemical furnaces, and other extreme high-temperature scenarios

II. Material Selection for Special Performance Needs

  1. Stress Corrosion Cracking (SCC) Risk Scenarios: Chloride-containing environments (e.g., swimming pools, marine), high temperature and humid environments. Recommended materials: D6/D8 Duplex steel, A8 Austenitic steel; Avoid: A1-A5 Austenitic steels.

  2. Pitting/Crevice Corrosion Resistance: Pitting Resistance Equivalent Number (PREN) = %Cr + 3.3 * %Mo + 16 * %N; For Duplex steels containing Tungsten (W): PREN = %Cr + 3.3 * (%Mo + 0.5 * %W) + 16 * %N. Recommended materials: Groups with high PREN values (e.g., A8, D8, D6), suitable for chemical media containing chlorine, seawater environments.

  3. Intergranular Corrosion Resistance: High-risk conditions: Carbon content > 0.03% + temperature range 550°C - 925°C (e.g., after welding, high temperature use). Recommended materials: Low-carbon groups: A2L, A4L (C ≤ 0.03%); Stabilized groups: A3, A5 (contain Ti/Nb, combines with carbon to prevent intergranular corrosion); Duplex steels: All groups D2-D8.

  4. Low/Non-Magnetic Requirements: Core materials: Austenitically stable grades, such as A2L (4311-304-53-I), A4L (4406-316-53-I), QN1803 (Nitrogen-alloyed Austenitic steel). Note: Cold working can produce weak residual magnetism; subsequent heat treatment can remove it if non-magnetic is required, or confirm permeability with supplier in advance (require relative permeability close to 1.0).

  5. High Strength + Anti-Galling: Recommended materials: Sorbitic high-strength stainless structural steel (S1 group): Suitable for large diameter, high load fasteners (e.g., large structural steel bolts), stable torque coefficient; QN1803 (A2 group nitrogen steel): High strength and weakly magnetic, low risk of galling during installation, suitable for frequent assembly/disassembly scenarios.

III. Common Stainless Steel Grades for Fasteners

Table 1: Cold Heading Fastener Stainless Steel Grades - Austenitic

ClassGroupISC CodeEuronorm Material NumberEuronorm DesignationASTM UNSUS Common GradeGB Code (China)

Sulfurized AusteniticA14305-303-00-11.4305X8CrNiS18-9S30300303Y1Cr18Ni9 (approx.)

4570-303-31-11.4570X6CrNiCuS18-9-2S30331303Cu-

General Purpose AusteniticA2L4307-304-03-11.4307X2CrNi18-9S30403304L022Cr19Ni10

4306-304-03-11.4306X2CrNi19-11S30403304L022Cr19Ni10

4311-304-53-I1.4311X2CrNiN18-9S30453304LN022Cr19Ni10N

A24301-304-00-I1.4301X5CrNi18-10S3040030406Cr19Ni10

4567-804-3011.4567X3CrNiCu18-9-4S30430304Cu06Cr18Ni9Cu3

4560-304-75-E1.4560X3CrNiCu19-9-2-304Cu-

4303-305-00-11.4303X4CrNi18-12S3050030518Cr15Ni12

Stabilized AusteniticA34550-347-00-11.4550X6CrNiNb18-10S3470034706Cr18Ni11Nb
4541-321-00-11.4541X6CrNiTi18-10S3210032106Cr18Ni11Ti

Molybdenum AusteniticA4L4401-315-00-11.4401X5CrNiMo17-12-2S3160031606Cr17Ni12Mo2

4404-315-03-11.4404X2CrNiMo17-12-2S31603316L022Cr17Ni12Mo2

4406-316-53-11.4406X2CrNiMoN17-11-2S31653316LN022Cr17Ni12Mo2N

4432-316-03-11.4432X2CrNiMo17-12-3S31603316L022Cr17Ni14Mo2

A4L/A44435-316-91-11.4435X2CrNiMo18-14-3S31603316L022Cr17Ni14Mo3

4436-316-00-11.4436X3CrNiMo17-13-3S3160031606Cr17Ni12Mo3

A44578-316-76-E1.4578X3CrNiCuMo17-11-3-2---

Stabilized Mo AusteniticA54571-316-35-11.4571X6CrNiMoTi17-12-2S31635316Ti06Cr17Ni12Mo2Ti

High-Mo Super AusteniticA84478-083-67-U1.4478X2NiCrMoN25-21-7N08367AL-6XN® / N08367-

4529-089-26-11.4529X1NiCrMoCuN25-20-7N08926926 / Alloy 926-

4547-312-54-11.4547X1CrNiMoCuN20-18-7S31254254 SMO / F44015Cr20Ni18Mo6CuN

Table 2: Cold Heading Fastener Stainless Steel Grades - Ferritic / Martensitic / Duplex

CategoryGroupISC CodeEuronorm Material NumberEuronorm DesignationASTM UNSUS Common GradeGB Code (China)
General Purpose MartensiticC14006-410-CO-I1.4006X12Cr13S4100041012Cr13
C14000-410-08-11.4000X6Cr13S41008410S06Cr13
C1, CH04021-420-00-11.4021X20Cr13S4200042020Cr13
C1, CH14028-420-00-11.4028X30Cr13S4200042030Cr13
C14034-420-CO-I1.4034X46Cr13S4200042040Cr13
High-Temp Martensitic?V, or VH4923-422-77-E1.4923X22CrMoV12-1---
High-Cr MartensiticC3, CH24057-431-0D-X1.4057X17CrNi16-2S4310043117Cr16Ni2
Free-Machining MartensiticC44005-416-00-11.4005X12CrS13S41600416Y1Cr13
C44029-420-20-11.4029X29CrS13S42020420FY3Cr13
FerriticF14016-430-00-11.4016X6Cr17S4300043010Cr17
F14511-430-71-I1.4511X3CrNb17--028Cr17? (Stabilized)
F14113-434-00-11.4113X6CrMo17-1S4340043410Cr17Mo
F14526-436-CO-I1.4526X6CrMoNb17-1S43600436028Cr17MoNb?
F14509-439-4D-X1.4509X2CrTiNb18S43940439 / 441?022Cr18Ti?
F14521-444-00-I1.4521X2CrMoTi18-2S44400444019Cr18MoTi?
DuplexD24482-320-01-X1.4482X2CrMnNiMoN21-5-3S320012001 / LDX 2101®-
























































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