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Principles of using high-temperature metallic materials

I. Performance Requirements for Metal Materials in High-Temperature Fasteners

High-temperature fastener materials must meet the following criteria:

  1. Strength & Plasticity: Good room temperature and high-temperature tensile strength with adequate ductility.

  2. Impact Resistance: Excellent impact energy absorption and low notch sensitivity.

  3. Anti-Relaxation: For carbon steels operating above 300–350°C and alloy steels above 350–400°C.

  4. Creep Resistance: High creep rupture strength, long-term stability, low creep embrittlement tendency, and ≥5% persistent elongation (new materials) or ≥3% (in-service materials) after 8,000–10,000 hours at temperature.

  5. Structural Stability: Minimal temper embrittlement and hot brittleness.

  6. Oxidation Resistance: Superior resistance to oxidation and thermal fatigue.

  7. Corrosion Resistance: Suitable corrosion resistance for bolts exposed to cylinder environments.

  8. Fatigue Resistance: High fatigue and shear strength for cyclically loaded applications (e.g., coupling bolts).

  9. Processability: Excellent cold/hot working characteristics.

  10. Compatibility: Nut materials should be 20–50 HB lower in hardness than bolts. Mixed-material fasteners on the same flange require consideration of thermal expansion mismatch and anti-relaxation performance.


II. Acceptance Criteria for High-Temperature Fastener Materials

  1. Comply with DL/T 439GB/T 20410, and contractual specifications.

  2. Imported materials must meet equivalent foreign standards (e.g., ASTM, ISO) and contractual requirements.


III. Commonly Used Metal Materials for Fasteners

Table: Steel Grades, Characteristics, and Maximum Service Temperatures

Steel Grade & Specification
Key Characteristics
Max. Service Temp. (°C)
Equivalent Grades (USSR)
35, 45 GB/T 699-1999
Low strength but adjustable hardness; good toughness and weldability.
400
35SiMn GB/T 3077-1999
Improved hardenability, moderate strength, prone to overheating and temper brittleness.
400
35CrMo GB/T 3077-1999
High strength, toughness, and creep resistance; requires preheating (150–400°C).
480
25Cr2MoVA GB/T 3077-1999
Austenitic heat-resistant steel with exceptional anti-relaxation at 500°C.
510
3M10 (USSR)
25Cr2Mo1VA
Enhanced high-temperature strength and oxidation resistance but prone to delayed cracking.
550
3M723 (USSR)
45Cr1MoVA
High-temperature strength via Mo/V additions; customizable heat treatment.
500
20Cr1Mo1V1A
Superior thermal stability up to 565°C; maintains strength after long-term service.
550
3M909 (USSR)
20Cr1Mo1VNbTiB
Advanced creep resistance and uniform mechanical properties.
570
2Cr12WMoVNbB
12% Cr-modified steel for operation up to 590°C with excellent relaxation resistance.
590
3M993 (USSR)
1Cr15Ni36W3Ti
Precipitation-hardened austenitic steel with 650°C creep strength and 5–8% elongation at 10,000 hours.
650
3M612 (USSR)
2Cr12NiMo1W1V
Low notch sensitivity and vibration damping; used in 12% Cr martensitic alloys.
570
C-422 (ASTM)
1Cr11MoNiW1VNbN
High-temperature strength and oxidation resistance via Nb/V/N additions.
650
Refractoloy-26 (R-26)
Ni-Cr-Co-based superalloy with 677°C creep strength and precipitation hardening.
677
1Cr11Co3W3NiMoVNbNB
Enhanced creep strength through W/Co synergistic effects.
650
GH 4145 (Ni-Cr Alloy)
High-temperature strength and oxidation resistance in Ni-Cr-Co alloys.
677
IN 783
Ni-Fe-Co low-expansion alloy with β-phase stabilization for turbine valves.

Note: Nuts may operate 30–50°C higher than bolts listed, with reduced hardness (20–50 HB lower).


Source: Adapted from DL/T 715-2015 Guidelines for Material Selection of Power Plant Metals.


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